Stable Compositions and Structures of Copper Oxide Cluster Cations Cu nO m + (n = 2-8) Studied by Ion Mobility Mass Spectrometry

M. Abdul Latif, Jenna W.J. Wu, Ryoichi Moriyama, Motoyoshi Nakano, Keijiro Ohshimo, Fuminori Misaizu

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5 Citations (Scopus)

Abstract

Stable compositions and structures of copper oxide cluster cations have been studied by ion mobility mass spectrometry (IMMS) and density functional theory calculations. Cluster ions of the series CunOm + were predominantly observed with n:m ≈ 2:1 in the mass spectrum. Collision cross sections (CCSs) of the cluster ions with n:m ≈ 2:1, determined by IMMS, were found to increase monotonically with cluster size. In addition, the CCSs of CunOn + and CunOn-1 + (n = 2-8) were examined, and stepwise increases were observed for CunOn-1 + series. These cluster structures were assigned by comparison of the CCSs obtained via the IMMS experiment with theoretical orientation-averaged CCSs of optimized structures.

Original languageEnglish
Pages (from-to)18705-18713
Number of pages9
JournalACS Omega
Volume3
Issue number12
DOIs
Publication statusPublished - 2018 Dec 28

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

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