Stability of SxSey ring clusters studied by Raman scattering

A. Kasuya, K. Watanabe, H. Takahashi, K. Toji, K. Motomiya, Y. Nishina

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

The compound clusters of SxSey have been crystallized by vacuum distillation. The raman scattering was measured from samples deposited along the region of the temperature gradient. The results show a systematic shift of the spectral peaks along the gradient, indicating that the SxSe8 - x with the larger values of x crystallized at lower temperatures. The crystal is in a rhombic structure which is not reported in the literature. Our experiments with liquid chromatography show that they are not stable in solution and are difficult to separate into single phases in solid form.

Original languageEnglish
Pages (from-to)12-14
Number of pages3
JournalMaterials Science and Engineering A
Volume217-218
DOIs
Publication statusPublished - 1996 Oct 30

Keywords

  • Crystals
  • Raman scattering
  • SSe

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

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