We grew single crystals of ullmannite NiSbS and PbBiSe with the cubic chiral structure and carried out electrical resistivity, specific heat, and de Haas-van Alphen (dHvA) experiments to clarify their Fermi surface properties. The Fermi surfaces were found to split into two, reflecting the non-centrosymmetric crystal structure. The splitting energies between the two nearly spherical electron Fermi surfaces named α and αPrime; were determined as 220K in NiSbS and 1050K in PdBiSe for H ¶  or . This difference in splitting energies between the two compounds originates mainly from the fact that the spin-orbit interactions of Ni-3d, Sb-5p, and S-3p electrons in NiSbS are smaller in magnitude than those of Pd-4d, Bi-6p, and Se-4p electrons in PdBiSe, respectively.
ASJC Scopus subject areas
- Physics and Astronomy(all)