Spin solitons in a halogen-bridged 1-D Pt complex

Noriyoshi Kimura, Shin'ichi Ishimaru, Hiroshi Okamoto, Masahiro Yamashita, Ryuichi Ikeda

Research output: Contribution to journalConference article

Abstract

Temperature and Larmor frequency dependences of 1H NMR relaxation time T1 were measured in a 1-D halogen-bridged complex [Pt(en)2][PtX2(en)2](ClO4)4 in ranges of 90 - 300 K and 15 - 60 MHz, respectively. The observed main and long T1 component was explainable by the magnetic dipolar relaxation due to electron spins diffusing along the 1-D chain containing paramagnetic PtIII sites with a concentration of 10-4 in molar ratio. These spins attributed to neutral spin solitons were shown to diffuse more rapidly than those in [Pd(chxn)2][PdBr2(chxn)2]Br4 forming 2-D H-bond networks

Original languageEnglish
Pages (from-to)2151-2152
Number of pages2
JournalSynthetic Metals
Volume86
Issue number1 -3 pt 3
DOIs
Publication statusPublished - 1997 Jan 1
Externally publishedYes
EventProceedings of the 1996 International Conference on Science and Technology of Synthetic Metals, ICSM'96. Part 3 (of 3) - Snowbird, UT, USA
Duration: 1996 Jul 281996 Aug 2

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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