Spin polarization transfer during the addition reaction of phosphorus radicals to simple olefins in solution

K. Akiyama; M. C. Depew; J. K.S. Wan

doi:10.1007/BF03051816

Spin polarization transfer during the addition reaction of phosphorus radicals to simple olefins in solution

K. Akiyama, M. C. Depew, J. K.S. Wan

Division of Organic- and Biomaterials Research

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

A CIDEP study of the radical adducts formed by addition of phosphonyl radicals to several unsaturated organic compounds is described. The complicated time-resolved ESR spectra obtained for these adducts were interpreted on the basis of competing chemical and physical processes involved in polarization transfer to the secondary radicals produced. This is a novel example illustrating for the first time radical pair polarization transfer in solution.

Original language	English
Pages (from-to)	25-36
Number of pages	12
Journal	Research on Chemical Intermediates
Volume	11
Issue number	1
DOIs	https://doi.org/10.1007/BF03051816
Publication status	Published - 1989 Feb 1

ASJC Scopus subject areas

Chemistry(all)

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10.1007/BF03051816

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title = "Spin polarization transfer during the addition reaction of phosphorus radicals to simple olefins in solution",

abstract = "A CIDEP study of the radical adducts formed by addition of phosphonyl radicals to several unsaturated organic compounds is described. The complicated time-resolved ESR spectra obtained for these adducts were interpreted on the basis of competing chemical and physical processes involved in polarization transfer to the secondary radicals produced. This is a novel example illustrating for the first time radical pair polarization transfer in solution.",

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AB - A CIDEP study of the radical adducts formed by addition of phosphonyl radicals to several unsaturated organic compounds is described. The complicated time-resolved ESR spectra obtained for these adducts were interpreted on the basis of competing chemical and physical processes involved in polarization transfer to the secondary radicals produced. This is a novel example illustrating for the first time radical pair polarization transfer in solution.

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