Spin polarization transfer during the addition reaction of phosphorus radicals to simple olefins in solution

K. Akiyama, M. C. Depew, J. K.S. Wan

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)

Abstract

A CIDEP study of the radical adducts formed by addition of phosphonyl radicals to several unsaturated organic compounds is described. The complicated time-resolved ESR spectra obtained for these adducts were interpreted on the basis of competing chemical and physical processes involved in polarization transfer to the secondary radicals produced. This is a novel example illustrating for the first time radical pair polarization transfer in solution.

Original languageEnglish
Pages (from-to)25-36
Number of pages12
JournalResearch on Chemical Intermediates
Volume11
Issue number1
DOIs
Publication statusPublished - 1989 Feb 1

ASJC Scopus subject areas

  • Chemistry(all)

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