Spectroscopic Analysis of Liquid/Liquid Interfaces in Multiphase Microflows

Akihide Hibara, Masaki Nonaka, Manabu Tokeshi, Takehiko Kitamori

Research output: Contribution to journalArticlepeer-review

47 Citations (Scopus)

Abstract

Microscopic quasi-elastic laser scattering (μQELS) spectroscopy has been developed for analysis of interfacial phenomena at laminar multiphase microflow in a microchannel. Transport phenomena of a metal chelate through a water/toluene interface were measured, and transient adsorption of the chelate in the initial step of the transport was measured. A water/methanol miscible interface was also measured, and the interfacial free energy of a miscible interface was determined for the first time. The μQELS is expected to be very effective not only for physicochemical investigations of transport and mixing, but also for elemental process analysis of heterogeneous reactions.

Original languageEnglish
Pages (from-to)14954-14955
Number of pages2
JournalJournal of the American Chemical Society
Volume125
Issue number49
DOIs
Publication statusPublished - 2003 Dec 10
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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