Sonochemical degradation of chlorophenols in water

Yoshio Nagata, Michiyo Nakagawa, Hiroshi Okuno, Yoshiteru Mizukoshi, Bongbeen Yim, Yasuaki Maeda

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157 Citations (Scopus)

Abstract

Sonochemical degradation of dilute aqueous solutions of 2-, 3- and 4-chlorophenol and pentachlorophenol has been investigated under air or argon atmosphere. The degradation follows first-order kinetics in the initial state with rates in the range 4.5-6.6 μM min-1 under air and 6.0-7.2 μM min-1 under argon at a concentration of 100 μM of chlorophenols. The rate of OH radical formation from water is 19.8 μM min-1 under argon and 14.7 μM min-1 under air in the same sonolysis conditions. The sonolysis of chlorophenols is effectively inhibited, but not completely, by the addition of t-BuOH, which is known to be an efficient OH radical scavenger in aqueous sonolysis. This suggests that the main degradation of chlorophenols proceeds via reaction with OH radicals; a thermal reaction also occurs, although its contribution is small. The addition of appropriate amounts of Fe(II) ions accelerates the degradation. This is probably due to the regeneration of OH radicals from hydrogen peroxide, which would be formed from recombination of OH radicals and which may contribute a little to the degradation. The ability to inhibit bacterial multiplication of pentachlorophenol decreases with ultrasonic irradiation.

Original languageEnglish
Pages (from-to)115-120
Number of pages6
JournalUltrasonics Sonochemistry
Volume7
Issue number3
DOIs
Publication statusPublished - 2000 Jul

Keywords

  • Chlorophenols
  • Pentachlorophenol
  • Sonochemical degradation

ASJC Scopus subject areas

  • Chemical Engineering (miscellaneous)
  • Environmental Chemistry
  • Radiology Nuclear Medicine and imaging
  • Acoustics and Ultrasonics
  • Organic Chemistry
  • Inorganic Chemistry

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  • Cite this

    Nagata, Y., Nakagawa, M., Okuno, H., Mizukoshi, Y., Yim, B., & Maeda, Y. (2000). Sonochemical degradation of chlorophenols in water. Ultrasonics Sonochemistry, 7(3), 115-120. https://doi.org/10.1016/S1350-4177(99)00039-5