Solvent switching of stereoselectivity in [4 + 4] photocyclodimerization of 2-anthracenecarboxylic acid

Jun Ichi Mizoguchi; Takehiko Wada; Yoshihisa Inoue

doi:10.1246/cl.2006.738

Solvent switching of stereoselectivity in [4 + 4] photocyclodimerization of 2-anthracenecarboxylic acid

Jun Ichi Mizoguchi, Takehiko Wada, Yoshihisa Inoue

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Stereochemistry of the major photocyclodimer is switched from 52% anti-head-to-head to 51% anti-head-to-tail among the four stereoisomers produced upon irradiation of 2-anthracenecarboxylic acid at low temperatures by changing the solvent from dichloromethane to methanol, through a critical control of the hydrogen bonding and dipole-dipole interactions.

Original language	English
Pages (from-to)	738-739
Number of pages	2
Journal	Chemistry Letters
Volume	35
Issue number	7
DOIs	https://doi.org/10.1246/cl.2006.738
Publication status	Published - 2006 Jul 5
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1246/cl.2006.738

Fingerprint Dive into the research topics of 'Solvent switching of stereoselectivity in [4 + 4] photocyclodimerization of 2-anthracenecarboxylic acid'. Together they form a unique fingerprint.

Cite this

@article{b308c81ab31b4e86937ea818daa3d7fb,

title = "Solvent switching of stereoselectivity in [4 + 4] photocyclodimerization of 2-anthracenecarboxylic acid",

abstract = "Stereochemistry of the major photocyclodimer is switched from 52% anti-head-to-head to 51% anti-head-to-tail among the four stereoisomers produced upon irradiation of 2-anthracenecarboxylic acid at low temperatures by changing the solvent from dichloromethane to methanol, through a critical control of the hydrogen bonding and dipole-dipole interactions.",

author = "Mizoguchi, {Jun Ichi} and Takehiko Wada and Yoshihisa Inoue",

year = "2006",

month = jul,

day = "5",

doi = "10.1246/cl.2006.738",

language = "English",

volume = "35",

pages = "738--739",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Chemical Society of Japan",

number = "7",

}

TY - JOUR

T1 - Solvent switching of stereoselectivity in [4 + 4] photocyclodimerization of 2-anthracenecarboxylic acid

AU - Mizoguchi, Jun Ichi

AU - Wada, Takehiko

AU - Inoue, Yoshihisa

PY - 2006/7/5

Y1 - 2006/7/5

N2 - Stereochemistry of the major photocyclodimer is switched from 52% anti-head-to-head to 51% anti-head-to-tail among the four stereoisomers produced upon irradiation of 2-anthracenecarboxylic acid at low temperatures by changing the solvent from dichloromethane to methanol, through a critical control of the hydrogen bonding and dipole-dipole interactions.

AB - Stereochemistry of the major photocyclodimer is switched from 52% anti-head-to-head to 51% anti-head-to-tail among the four stereoisomers produced upon irradiation of 2-anthracenecarboxylic acid at low temperatures by changing the solvent from dichloromethane to methanol, through a critical control of the hydrogen bonding and dipole-dipole interactions.

UR - http://www.scopus.com/inward/record.url?scp=33749347874&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33749347874&partnerID=8YFLogxK

U2 - 10.1246/cl.2006.738

DO - 10.1246/cl.2006.738

M3 - Article

AN - SCOPUS:33749347874

VL - 35

SP - 738

EP - 739

JO - Chemistry Letters

JF - Chemistry Letters

SN - 0366-7022

IS - 7

ER -

Solvent switching of stereoselectivity in [4 + 4] photocyclodimerization of 2-anthracenecarboxylic acid

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Cite this