Solvent-mediated tuning of the regioselectivity of intramolecular diaryl ether formation: Total synthesis of (+)-aspercyclide C

Tatsuya Yoshino, Shuji Yamashita, Itaru Sato, Yujiro Hayashi, Masahiro Hirama

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

A concise total synthesis of the 11-membered cyclic (+)-aspercyclide C is reported. Key to success was the fine-tuning of the reaction media to realize an oxidative, macrocyclic diaryl C-O bond formation in a regioselective and direct fashion.

Original languageEnglish
Pages (from-to)349-351
Number of pages3
JournalChemistry Letters
Volume43
Issue number3
DOIs
Publication statusPublished - 2014

ASJC Scopus subject areas

  • Chemistry(all)

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