Solvent isotope effect and mechanism for the production of hydrogen and lactic acid from glycerol under hydrothermal alkaline conditions

Yalei Zhang; Zheng Shen; Xuefei Zhou; Min Zhang; Fangming Jin

doi:10.1039/c2gc36153a

Solvent isotope effect and mechanism for the production of hydrogen and lactic acid from glycerol under hydrothermal alkaline conditions

Yalei Zhang, Zheng Shen, Xuefei Zhou, Min Zhang, Fangming Jin

ENV - Environmental Studies for Advanced Society

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

To discover the reaction mechanism for the production of hydrogen and lactic acid from glycerol under alkaline hydrothermal conditions, we identified the different intermediates involved during reactions by investigating the solvent isotope effect with ¹H-NMR, ²H-NMR, LC-MS and Gas-MS analyses, and then proposed and proved a potential reaction mechanism.

Original language	English
Pages (from-to)	3285-3288
Number of pages	4
Journal	Green Chemistry
Volume	14
Issue number	12
DOIs	https://doi.org/10.1039/c2gc36153a
Publication status	Published - 2012 Dec 1

ASJC Scopus subject areas

Environmental Chemistry
Pollution

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abstract = "To discover the reaction mechanism for the production of hydrogen and lactic acid from glycerol under alkaline hydrothermal conditions, we identified the different intermediates involved during reactions by investigating the solvent isotope effect with 1H-NMR, 2H-NMR, LC-MS and Gas-MS analyses, and then proposed and proved a potential reaction mechanism.",

author = "Yalei Zhang and Zheng Shen and Xuefei Zhou and Min Zhang and Fangming Jin",

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AU - Zhang, Yalei

AU - Shen, Zheng

AU - Zhou, Xuefei

AU - Zhang, Min

AU - Jin, Fangming

PY - 2012/12/1

Y1 - 2012/12/1

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AB - To discover the reaction mechanism for the production of hydrogen and lactic acid from glycerol under alkaline hydrothermal conditions, we identified the different intermediates involved during reactions by investigating the solvent isotope effect with 1H-NMR, 2H-NMR, LC-MS and Gas-MS analyses, and then proposed and proved a potential reaction mechanism.

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Solvent isotope effect and mechanism for the production of hydrogen and lactic acid from glycerol under hydrothermal alkaline conditions

Abstract

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