Solvent free amination reactions of aryl bromides at room temperature catalyzed by a (π-allyl)palladium complex bearing a diphosphinidenecyclobutene ligand

Anil S. Gajare, Kozo Toyota, Masaaki Yoshifuji, Fumiyuki Ozawa

Research output: Contribution to journalArticle

46 Citations (Scopus)

Abstract

An air- and moisture-stable (π-allyl)palladium complex bearing a unique diphosphinidenecyclobutene ligand effectively catalyzes amination reactions of aryl bromides with amines, where the reactions proceed under mild conditions without solvent, with 2 mol % of catalyst and 1 equiv of t-BuOK at room temperature. Under these conditions the amination products were obtained in good to excellent isolated yields.

Original languageEnglish
Pages (from-to)6504-6506
Number of pages3
JournalJournal of Organic Chemistry
Volume69
Issue number19
DOIs
Publication statusPublished - 2004 Sep 17

ASJC Scopus subject areas

  • Organic Chemistry

Fingerprint Dive into the research topics of 'Solvent free amination reactions of aryl bromides at room temperature catalyzed by a (π-allyl)palladium complex bearing a diphosphinidenecyclobutene ligand'. Together they form a unique fingerprint.

  • Cite this