Solubility of trifluoroethoxyphthalocyanines and -subphthalocyanines in liquid and supercritical carbon dioxide

Banibrata Das, Etsuko Tokunaga, Norio Shibata, Nagao Kobayashi

Research output: Contribution to journalArticlepeer-review

15 Citations (Scopus)

Abstract

In an analysis of the solubility of a wide range of phthalocyanines (Pcs) and its analogues (SubPcs) in liquid and/or supercritical CO2, compounds with trifluoroethoxy substituents were found to exhibit high solubility. To our knowledge, this is the first example of Pc compounds soluble in 100% CO2. This unprecedented unique property of trifluoroethoxy substituted Pcs might have particular applications in catalysis in organic reactions as well as dyes for solar cells by CO2 delivering coatings.

Original languageEnglish
Pages (from-to)652-654
Number of pages3
JournalJournal of Fluorine Chemistry
Volume131
Issue number5
DOIs
Publication statusPublished - 2010 May 1

Keywords

  • Carbon dioxide
  • Phthalocyanine
  • Solubility
  • Subphthalocyanine

ASJC Scopus subject areas

  • Biochemistry
  • Environmental Chemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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