Solubility of hydrogen sulfide in isooctane, n-decane, n-tridecane, n-hexadecane and squalane at temperatures from 323 to 523 K and pressures up to 1.6 MPa

Chiaki Yokoyama, Akito Usui, Shinji Takahashi

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14 Citations (Scopus)

Abstract

Yokoyama, C., Usui, A. and Takahashi, S., 1993. Solubility of hydrogen sulfide in isooctane, n-decane, n-tridecane, n-hexadecane and squalane at temperatures from 323 to 523 K and pressures up to 1.6 MPa. Fluid Phase Equilibria, 85: 257-269. The solubility of hydrogen sulfide (H2S) in isooctane, n-decane, n-tridecane, n-hexadecane and squalane has been experimentally determined for the temperature range 323-523 K and pressures up to 1.6 MPa. Henry's constants have been determined from the solubility data according to the Krichevsky-Kasanovsky equation. The Soave-Redlich-Kwong (SRK) and the Peng-Robinson (PR) equations of state were used to calculate the solubility data. The binary interaction parameter of the PR equation was correlated with the ratio of the critical volumes of H2S and hydrocarbons.

Original languageEnglish
Pages (from-to)257-269
Number of pages13
JournalFluid Phase Equilibria
Volume85
Issue numberC
DOIs
Publication statusPublished - 1993 May 15

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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