Solid-phase synthesis of phthalocyanine and tetraazaporphyrin triangular prisms

Atsuya Muranaka, Kengo Yoshida, Yusuke Akagi, Hiroshi Naka, Masanobu Uchiyama, Yoshinori Kondo, Nagao Kobayashi

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

A solvent-free, solid-phase one-step reaction between tetra-tert-butylated oxotitanium(IV) phthalocyanine and tetraazaporphyrin with 2,3,6,7,10,11-hexahydroxytriphenylene yields novel azaporphyrin cyclic trimers with triangular prismatic orientations. The fluorescence arising from the phthalocyanine and tetraazaporphyrin chromophores is significantly quenched upon trimerization.

Original languageEnglish
Pages (from-to)5084-5086
Number of pages3
JournalTetrahedron Letters
Volume49
Issue number34
DOIs
Publication statusPublished - 2008 Aug 18

Keywords

  • Phthalocyanines
  • Solid-phase synthesis
  • Tetraazaporphyrins

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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