Soft X-ray emission spectroscopy study of electronic structure of sodium borosilicide Na8B74.5Si17.5

Masami Terauchi, Haruhiko Morito, Hisanori Yamane, Shogo Koshiya, Koji Kimoto

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

Chemical bonding state of sodium borosilicide Na8B74.5Si17.5, which is a new member of B12-cluster materials, is investigated by soft X-ray emission spectroscopy. The material is composed of B12 cluster network and characteristic silicon chains of [-Si-(Si-Si)3-Si-] connected by sp3 bonding, in which bonding distances and bonding angles are close to those in cubic Si crystal. B K-emission spectrum of the material showed a similar but a broader intensity distribution with those of B12 cluster materials of α-r-B, B4C and β-r-B. The broader intensity distribution can be due to a variation of B-B bond length in B12 cluster. The density of states (DOS) of silicon chains of [-Si-(Si-Si)3-Si-] was experimentally derived. It shows a similar energy width, and peak or shoulder structures in intensity distribution with those of L-emission spectrum of cubic Si. From comparisons between experimental spectra and corresponding calculated DOS, covalent bonding between Si chain and B12 cluster network is suggested. Those are discussed by using a theoretically calculated density of state of Na8B74.5Si17.5 by using WIEN2k code.

Original languageEnglish
Pages (from-to)i72-i77
JournalMicroscopy
Volume67
DOIs
Publication statusPublished - 2018 Mar 1

Keywords

  • B K-emission
  • Bonding states
  • Si L-emission
  • Sodium borosilicide
  • Soft X-ray emission spectroscopy

ASJC Scopus subject areas

  • Structural Biology
  • Instrumentation
  • Radiology Nuclear Medicine and imaging

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