Sodium superionic conduction in Na2B12H12

Terrence J. Udovic, Motoaki Matsuo, Atsushi Unemoto, Nina Verdal, Vitalie Stavila, Alexander V. Skripov, John J. Rush, Hitoshi Takamura, Shin Ichi Orimo

Research output: Contribution to journalArticlepeer-review

139 Citations (Scopus)

Abstract

Impedance measurements indicate that Na2B12H12 exhibits dramatic Na+ conductivity (on the order of 0.1 S cm−1) above its order-disorder phase-transition at ≈529 K, rivaling that of current, solid-state, ceramic-based, Na-battery electrolytes. Superionicity may be aided by the large size, quasispherical shape, and high rotational mobility of the B12H122− anions.

Original languageEnglish
Pages (from-to)3750-3752
Number of pages3
JournalChemical Communications
Volume50
Issue number28
DOIs
Publication statusPublished - 2014 Mar 11

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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