Sn Nanoparticles Confined in Porous Silica Spheres for Enhanced Thermal Cyclic Stability

Shilei Zhu, Mai Thanh Nguyen, Koji Fumoto, Kiyoshi Kanie, Atsushi Muramatsu, Tetsu Yonezawa

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

We report a facile method for preparing a silica (SiO2)-based material containing Sn nanoparticles (NPs) distributed inside for enhancing the thermal cyclic stability of the inserted Sn NPs. Absorption of a Sn precursor (i.e., an aqueous SnCl2 solution) into a mesoporous SiO2 matrix resulted in confinement of the Sn precursor in a mesoporous SiO2 matrix. Hydrogen thermal reduction of the above composite yielded Sn nanoparticles with a diameter of ca. 30 nm uniformly distributed inside porous SiO2 (p-SiO2) spheres: Sn NPs@p-SiO2. Our investigation of the transformation of the porous SiO2 structure to hold Sn NPs revealed that the process was closely related to the transformation of the amorphous hydrolyzed Sn precursor into Sn oxides followed by, probably, the rearrangement of the SiO2 matrix via its interaction with the melting Sn. This led to the formation of stable Sn NPs@p-SiO2. The SiO2 matrix effectively prevented the coalescence of the Sn NPs, and the obtained product exhibited negligible changes in melting behavior during the second to 100th cycle of a freeze-melt cycle test. ©

Original languageEnglish
Pages (from-to)4073-4082
Number of pages10
JournalACS Applied Nano Materials
Volume1
Issue number8
DOIs
Publication statusPublished - 2018 Aug 24

Keywords

  • Sn
  • nanocomposite
  • porous silica sphere
  • thermal stability

ASJC Scopus subject areas

  • Materials Science(all)

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