TY - JOUR
T1 - Skeletal isomerism within 1,3-disilabicyclo[1.1.0]butane and 2,3-disilabuta-1,3-diene derivatives
AU - Iwamoto, Takeaki
AU - Kobayashi, Akifumi
AU - Akasaka, Naohiko
AU - Ishida, Shintaro
N1 - Funding Information:
This work was supported by JSPS KAKENHI (grant no. 25248010, T.I.).
Publisher Copyright:
© 2022
PY - 2022/1/1
Y1 - 2022/1/1
N2 - A bis-adamantane-spiro-fused 1,3-bis(triisopropylsilyl)-1,3-disilabicyclo[1.1.0]butane equilibrates with the corresponding 2,3-bis(triisopropylsilyl)-1,3-disilabuta-1,3-diene with a ratio of 1:19. The 1,3-disilabuta-1,3-diene was fully characterized by a combination of multinuclear NMR and UV-VIS spectroscopies, elemental analysis, and single-crystal X-ray diffraction analysis.
AB - A bis-adamantane-spiro-fused 1,3-bis(triisopropylsilyl)-1,3-disilabicyclo[1.1.0]butane equilibrates with the corresponding 2,3-bis(triisopropylsilyl)-1,3-disilabuta-1,3-diene with a ratio of 1:19. The 1,3-disilabuta-1,3-diene was fully characterized by a combination of multinuclear NMR and UV-VIS spectroscopies, elemental analysis, and single-crystal X-ray diffraction analysis.
KW - 1,3-Disilabicyclo[1.1.0]butanes
KW - 2,3-Disilabuta-1,3-dienes
KW - Bicyclo[1.1.0]butanes
KW - Organosilicon compounds
KW - Skeletal isomerization
KW - Tetrasilanes
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U2 - 10.1016/j.mencom.2022.01.012
DO - 10.1016/j.mencom.2022.01.012
M3 - Article
AN - SCOPUS:85125590530
SN - 0959-9436
VL - 32
SP - 39
EP - 41
JO - Mendeleev Communications
JF - Mendeleev Communications
IS - 1
ER -