Site-specific fragmentation caused by core-level photoionization in F 3 SiCH2 CH2 Si (CH33 vapor: Comparison between Si:1s and 2p photoionizations by means of photoelectron-photoion-photoion triple-coincidence spectroscopy

Shin Ichi Nagaoka, Mai Takemoto, Georg Prümper, Hironobu Fukuzawa, Yusuke Tamenori, Isao H. Suzuki, Kiyoshi Ueda

Research output: Contribution to journalArticlepeer-review

20 Citations (Scopus)

Abstract

Site-specific fragmentation caused by Si:1s and 2p core-level photoionizations in F3 SiCH2 CH2 Si (CH 33 vapor was studied by energy-selected-photoelectron photoion-photoion triple-coincidence spectroscopy. The difference between the chemical shifts of the two Si sites is larger for the 1s ionization than for the 2p (2s) ionization. The fragmentation caused by the Si:1s ionization is more violent than that caused by the Si:2p ionization. The ions and ion pairs showing high site specificity for the Si:1s ionization belong to small fragments compared to those in the Si:2p ionization. Criteria for high site-specificity in fragmentation are discussed in conjunction with the present results.

Original languageEnglish
Article number204309
JournalJournal of Chemical Physics
Volume129
Issue number20
DOIs
Publication statusPublished - 2008

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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