Site-specific electronic structures of ferrimagnetic Fe3O 4 measured by resonant X-ray magnetic scattering

Maki Okube, Satoshi Sasaki

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)


Resonant magnetic scattering of circularly polarized synchrotron X-rays has revealed the site-specific magnetic moments at two non-equivalent Fe ion sites in Fe3O4. The energy-dependent peaks for the 026 and 266 reflections were attributed ferrimagnetically to the e and t2 energy levels of Fe 3d at the A site, and to the t2g and e g levels at the B site, respectively, having a sequence of t2g, e, eg and t2 in order of energy. This sequence alphaees with the local spin-density approximation calculations in the literature [Anisimov, Elfimov, Hamada & Terakura, (1996). Phys. Rev. 54, 4387-4390], in which the spin-down band at the Fermi energy corresponds to t2g. Resonant magnetic Fourier synthesis reveals the electron densities of the ferrimagnetic moments.

Original languageEnglish
Pages (from-to)1387-1394
Number of pages8
JournalJournal of Applied Crystallography
Issue number4
Publication statusPublished - 2014 Aug
Externally publishedYes


  • electronic structure
  • ferrimagnetic Fe arrange="stagger"3O arrange="stagger"4
  • resonant X-ray magnetic scattering
  • site specificity

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)


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