Site selectivity of alkali metal ions in KxRb3-xC60

Ichiro Hirosawa, Jun'ichiro Mizuki, Katsumi Tanigaki, Hidekazu Kimura

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

We observed crystal structures of KxRb3-xC60 by X-ray diffraction, and found that Rb ions preferentially occupied octahedral interstitial sites. In the case of K2RbC60, Rb and K ions are accommodated in octahedral and tetrahedral sites respectively. As for the case of KRb2C60, Rb and K ions in tetrahedral interstitial sites were found to be in a random fashion by anomalous X-ray diffraction.

Original languageEnglish
Pages (from-to)55-58
Number of pages4
JournalSolid State Communications
Volume89
Issue number1
DOIs
Publication statusPublished - 1994 Jan
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)
  • Condensed Matter Physics
  • Materials Chemistry

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