Site-specific fragmentation caused by C KVV and F KVV Auger decay of free CH3F molecules has been studied. Energy-resolved Auger electrons and pairs of mass-resolved ions were detected in coincidence. Strong enhancements for the production of CH3+ s(-) F+ and H+-CF+ ion pairs were found for the F KVV and C KVV Auger decays, respectively.
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry