Site selective behavior of alkali metals in binary doped C60

I. Hirosawa, K. Tanigaki, J. Mizuki, T. W. Ebbesen, Y. Shimakawa, Y. Kubo, S. Kuroshima

Research output: Contribution to journalArticlepeer-review

21 Citations (Scopus)

Abstract

The site selective behavior of binary doped C60 superconductors with compositions of A2Cs1C60 and A1Cs2C60 (A=Na, K, Rb) was observed by X-ray diffraction. All the A2Cs1C60's indicate the ordering between octahedral and tetrahedral sites, while the situations for the A1Cs2C60 compositions are different depending on the kind of metal A. It is shown that the relationship between the ionic radius of metal A and the size of tetrahedral site plays an important role in site selectivity.

Original languageEnglish
Pages (from-to)979-982
Number of pages4
JournalSolid State Communications
Volume82
Issue number12
DOIs
Publication statusPublished - 1992 Jun
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)
  • Condensed Matter Physics
  • Materials Chemistry

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