Single photon K-2 and K-1K-1 double core ionization in C2H2n (n=1-3), CO, and N2 as a potential new tool for chemical analysis

M. Nakano, F. Penent, M. Tashiro, T. P. Grozdanov, M. Žitnik, S. Carniato, P. Selles, L. Andric, P. Lablanquie, J. Palaudoux, E. Shigemasa, H. Iwayama, Y. Hikosaka, K. Soejima, I. H. Suzuki, N. Kouchi, K. Ito

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Abstract

We have observed single photon double K-shell photoionization in the C 2H2n (n=1-3) hydrocarbon sequence and in N2 and CO, using synchrotron radiation and electron coincidence spectroscopy. Our previous observations of the K-2 process in these molecules are extended by the observations of a single photon double photoionization with one core hole created at each of the two neighboring atoms in the molecule (K -1K-1 process). In the C2H2n sequence, the spectroscopy of K-1K-1 states is much more sensitive to the bond length than conventional electron spectroscopy for chemical analysis spectroscopy based on single K-shell ionization. The cross section variation for single photon K-1K-1 double core ionization in the C2H2n sequence and in the isoelectronic C2H2, N2 and CO molecules validates a knock-out mechanism in which a primary ionized 1s photoelectron ejects another 1s electron of the neighbor atom. The specific Auger decay from such states is clearly observed in the CO case.

Original languageEnglish
Article number163001
JournalPhysical review letters
Volume110
Issue number16
DOIs
Publication statusPublished - 2013 Apr 18
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy(all)

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