Single-crystal-to-single-crystal transformation of diolefin derivatives in nanocrystals

Shu Takahashi, Hirohiko Miura, Hitoshi Kasai, Shuji Okada, Hidetoshi Oikawa, Hachiro Nakanishi

    Research output: Contribution to journalArticlepeer-review

    121 Citations (Scopus)

    Abstract

    Topochemical [2 + 2] cycloaddition polymerization of methyl p-phenylenediacrylate and 2,5-distyrylpyridine in nanocrystals, prepared by the reprecipitation method, were investigated in comparison with those in bulk crystals. The bulk single crystals, larger than 1 μm in size, broke into microcrystals with variety of size and shape in the course of polymerization. Interestingly, however, these nanocrystals show single-crystal-to-single-crystal transformation.

    Original languageEnglish
    Pages (from-to)10944-10945
    Number of pages2
    JournalJournal of the American Chemical Society
    Volume124
    Issue number37
    DOIs
    Publication statusPublished - 2002 Sep 18

    ASJC Scopus subject areas

    • Catalysis
    • Chemistry(all)
    • Biochemistry
    • Colloid and Surface Chemistry

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