Single-component molecular conductor [Zn(tmdt)2] and related Zn complexes

Kimiko Yamamoto, Emiko Fujiwara, Akiko Kobayashi, Yuichi Fujishiro, Eiji Nishibori, Makoto Sakata, Masaki Takata, Hisashi Tanaka, Yoshinori Okano, Hayao Kobayashi

Research output: Contribution to journalArticlepeer-review

14 Citations (Scopus)

Abstract

Single-component molecular conductors based on zinc complexes with filled 3d shells and extended-TTF ligands, [ZnL2] (L = tmdt, dmdt, and dt) were prepared. The crystal structure of semiconducting [Zn(tmdt)2] (ρ (rt) ≈ 50 Ω cm) was determined by the synchrotron radiation X-ray powder diffraction experiments. The molecule has a tetrahedral geometry and two ligand planes are almost perpendicular to each other.

Original languageEnglish
Pages (from-to)1090-1091
Number of pages2
JournalChemistry Letters
Volume34
Issue number8
DOIs
Publication statusPublished - 2005 Aug 5
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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