Silylene to Dlsllene and Dlsllene to Silylene Rearrangements

Hldekl Sakural; Yasuhlro Nakadalra; Hiroyuki Sakaba

doi:10.1021/om50004a052

Silylene to Dlsllene and Dlsllene to Silylene Rearrangements

Hldekl Sakural, Yasuhlro Nakadalra, Hiroyuki Sakaba

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

The silylene to dlsllene rearrangement was further confirmed by generating Me₃SIMe₂SIMeSI: from 3-methoxyundecamethylpentasilane to afford Me₂Si= SIMe(SiMe₃). However, at the same time the reverse rearrangement from the latter dlsllene to the former dl-sllanylsilylene was also demonstrated by generating Me₂Si=SiMe(SiMe₃). Results of photochemically generated disilanylsilylene and silyldisilene were compared with those of thermal reactions.

Original language	English
Pages (from-to)	1484-1486
Number of pages	3
Journal	Organometallics
Volume	2
Issue number	10
DOIs	https://doi.org/10.1021/om50004a052
Publication status	Published - 1983 Jan 1

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "Silylene to Dlsllene and Dlsllene to Silylene Rearrangements",

abstract = "The silylene to dlsllene rearrangement was further confirmed by generating Me3SIMe2SIMeSI: from 3-methoxyundecamethylpentasilane to afford Me2Si= SIMe(SiMe3). However, at the same time the reverse rearrangement from the latter dlsllene to the former dl-sllanylsilylene was also demonstrated by generating Me2Si=SiMe(SiMe3). Results of photochemically generated disilanylsilylene and silyldisilene were compared with those of thermal reactions.",

author = "Hldekl Sakural and Yasuhlro Nakadalra and Hiroyuki Sakaba",

year = "1983",

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doi = "10.1021/om50004a052",

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T1 - Silylene to Dlsllene and Dlsllene to Silylene Rearrangements

AU - Sakural, Hldekl

AU - Nakadalra, Yasuhlro

AU - Sakaba, Hiroyuki

PY - 1983/1/1

Y1 - 1983/1/1

N2 - The silylene to dlsllene rearrangement was further confirmed by generating Me3SIMe2SIMeSI: from 3-methoxyundecamethylpentasilane to afford Me2Si= SIMe(SiMe3). However, at the same time the reverse rearrangement from the latter dlsllene to the former dl-sllanylsilylene was also demonstrated by generating Me2Si=SiMe(SiMe3). Results of photochemically generated disilanylsilylene and silyldisilene were compared with those of thermal reactions.

AB - The silylene to dlsllene rearrangement was further confirmed by generating Me3SIMe2SIMeSI: from 3-methoxyundecamethylpentasilane to afford Me2Si= SIMe(SiMe3). However, at the same time the reverse rearrangement from the latter dlsllene to the former dl-sllanylsilylene was also demonstrated by generating Me2Si=SiMe(SiMe3). Results of photochemically generated disilanylsilylene and silyldisilene were compared with those of thermal reactions.

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JO - Organometallics

JF - Organometallics

IS - 10

ER -

Silylene to Dlsllene and Dlsllene to Silylene Rearrangements

Abstract

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