Silylene to Dlsllene and Dlsllene to Silylene Rearrangements

Hldekl Sakural, Yasuhlro Nakadalra, Hiroyuki Sakaba

Research output: Contribution to journalArticlepeer-review

38 Citations (Scopus)

Abstract

The silylene to dlsllene rearrangement was further confirmed by generating Me3SIMe2SIMeSI: from 3-methoxyundecamethylpentasilane to afford Me2Si= SIMe(SiMe3). However, at the same time the reverse rearrangement from the latter dlsllene to the former dl-sllanylsilylene was also demonstrated by generating Me2Si=SiMe(SiMe3). Results of photochemically generated disilanylsilylene and silyldisilene were compared with those of thermal reactions.

Original languageEnglish
Pages (from-to)1484-1486
Number of pages3
JournalOrganometallics
Volume2
Issue number10
DOIs
Publication statusPublished - 1983 Jan 1

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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