Silyl-pyridine-amine pincer-ligated iridium complexes for catalytic silane deuteration: Via room temperature C-D bond activation of benzene- d 6

Takashi Komuro, Tomohiro Osawa, Ryuju Suzuki, Daiki Mochizuki, Hironori Higashi, Hiromi Tobita

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

Iridium-hydrido complexes bearing a hemilabile silyl-pyridine-amine pincer ligand were synthesised. They were found to catalyse Si-H deuteration of trialkylsilanes with excess benzene-d6 in 99-94% conversion at room temperature through C-D bond activation and H/D exchange.

Original languageEnglish
Pages (from-to)957-960
Number of pages4
JournalChemical Communications
Volume55
Issue number7
DOIs
Publication statusPublished - 2019

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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