Silane(silyl) and Bis(silyl)hydrido manganese complexes with different Mn H Si interaction: Observation of gradual SiH bond activation on the metal center

Takashi Komuro, Satoshi Okawara, Keisuke Furuyama, Hiromi Tobita

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Three manganesecarbonyl complexes having a xanthenebased silane(silyl) or bis(silyl) chelate ligand were synthesized and characterized. The single-crystal X-ray analysis of these complexes demonstrated that an SiH bond is sequentially activated on the metal according to ligand substitution of CO with xanthene-oxygen or ?6-toluene.

Original languageEnglish
Pages (from-to)774-776
Number of pages3
JournalChemistry Letters
Volume41
Issue number8
DOIs
Publication statusPublished - 2012 Aug 6

ASJC Scopus subject areas

  • Chemistry(all)

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