Significant stabilization of palladium by gold in the bimetallic nanocatalyst leading to an enhanced activity in the hydrodechlorination of aryl chlorides

Sangita Karanjit; Atchaleeya Jinasan; Ekasith Samsook; Raghu N. Dhital; Kenichi Motomiya; Yoshinori Sato; Kazuyuki Tohji; Hidehiro Sakurai

doi:10.1039/c5cc04432d

Significant stabilization of palladium by gold in the bimetallic nanocatalyst leading to an enhanced activity in the hydrodechlorination of aryl chlorides

Sangita Karanjit, Atchaleeya Jinasan, Ekasith Samsook, Raghu N. Dhital, Kenichi Motomiya, Yoshinori Sato, Kazuyuki Tohji, Hidehiro Sakurai

ENV - Environmental Studies for Advanced Society

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

The stabilization effect of Au towards Pd changed the reactivity of Pd in Au/Pd bimetallic nanoclusters, altering the reaction mechanism from homogeneous to heterogeneous in dechlorination reaction of aryl chlorides. This phenomenon was illustrated by the observed enhancement of the rate of reaction by in situ generated Au-rich bimetallic Au/Pd nanoclusters.

Original language	English
Pages (from-to)	12724-12727
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	64
DOIs	https://doi.org/10.1039/c5cc04432d
Publication status	Published - 2015 Aug 18

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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Significant stabilization of palladium by gold in the bimetallic nanocatalyst leading to an enhanced activity in the hydrodechlorination of aryl chlorides. / Karanjit, Sangita; Jinasan, Atchaleeya; Samsook, Ekasith; Dhital, Raghu N.; Motomiya, Kenichi; Sato, Yoshinori; Tohji, Kazuyuki; Sakurai, Hidehiro.

In: Chemical Communications, Vol. 51, No. 64, 18.08.2015, p. 12724-12727.

Research output: Contribution to journal › Article › peer-review

Karanjit, Sangita ; Jinasan, Atchaleeya ; Samsook, Ekasith ; Dhital, Raghu N. ; Motomiya, Kenichi ; Sato, Yoshinori ; Tohji, Kazuyuki ; Sakurai, Hidehiro. / Significant stabilization of palladium by gold in the bimetallic nanocatalyst leading to an enhanced activity in the hydrodechlorination of aryl chlorides. In: Chemical Communications. 2015 ; Vol. 51, No. 64. pp. 12724-12727.

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AU - Jinasan, Atchaleeya

AU - Samsook, Ekasith

AU - Dhital, Raghu N.

AU - Motomiya, Kenichi

AU - Sato, Yoshinori

AU - Tohji, Kazuyuki

AU - Sakurai, Hidehiro

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Significant stabilization of palladium by gold in the bimetallic nanocatalyst leading to an enhanced activity in the hydrodechlorination of aryl chlorides

Abstract

ASJC Scopus subject areas

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