Significant solvent effect in anomerization reaction of pyranosides with 2,3-trans carbamate and carbonate

Shino Manabe, Yukishige Ito

Research output: Contribution to journalArticlepeer-review

16 Citations (Scopus)

Abstract

A pronounced solvent effect was observed in the anomerization reaction of pyranosides carrying 2,3-trans carbamate or carbonate. While significant anomerization from the β- to α-direction was observed in CH3CN, none was observed in ether.

Original languageEnglish
Pages (from-to)4827-4829
Number of pages3
JournalTetrahedron Letters
Volume50
Issue number34
DOIs
Publication statusPublished - 2009 Aug 26
Externally publishedYes

Keywords

  • Anomerization
  • Endocyclic cleavage
  • Pyranosides
  • Solvent effect

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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