Sequential palladium-catalyzed coupling reactions on solid-phase

Takayuki Doi, Hitoshi Inoue, Masatoshi Tokita, Junji Watanabe, Takashi Takahashi

Research output: Contribution to journalArticlepeer-review

29 Citations (Scopus)


Six-types of palladium-catalyzed coupling, Mizoroki-Heck, Migita-Stille, Sonogashira, carbonylative esterification, carbonylative Stille, and carbonylative Sonogashira reactions, were performed on a polymer support. The above coupling reactions of m- and p-substituted aromatic rings, followed by carbonylative esterification with m- and p-substituted anisol derivatives were carried out in a combinatorial manner. Acid cleavage from the polymer-support provided the conjugated aromatic ring systems 1 and 2, which are the core parts of rodlike liquid crystals.

Original languageEnglish
Pages (from-to)135-141
Number of pages7
JournalJournal of Combinatorial Chemistry
Issue number1
Publication statusPublished - 2008 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)


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