Sequential click modification of a lithium-ion endohedral fullerene connecting small molecules through a dieneazide linker

Shogo Fujiki; Takumi Takada; Shota Nagasawa; Hiroshi Okada; Yusuke Sasano; Eunsang Kwon; Yutaka Matsuo; Yoshiharu Iwabuchi

doi:10.1039/d2cc06301h

Sequential click modification of a lithium-ion endohedral fullerene connecting small molecules through a dieneazide linker

Shogo Fujiki, Takumi Takada, Shota Nagasawa, Hiroshi Okada, Yusuke Sasano, Eunsang Kwon, Yutaka Matsuo, Yoshiharu Iwabuchi

Research output: Contribution to journal › Article › peer-review

Abstract

A versatile method for the chemical modification of a lithium-ion endohedral fullerene (Li⁺@C₆₀) to connect various small molecules is described. The designed dieneazide linker enables the facile connection of Li⁺@C₆₀ with small molecules bearing a terminal alkyne via Huisgen annulation and a subsequent Diels-Alder reaction.

Original language	English
Pages (from-to)	1237-1240
Number of pages	4
Journal	Chemical Communications
Volume	59
Issue number	9
DOIs	https://doi.org/10.1039/d2cc06301h
Publication status	Published - 2023 Jan 4

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/d2cc06301h

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abstract = "A versatile method for the chemical modification of a lithium-ion endohedral fullerene (Li+@C60) to connect various small molecules is described. The designed dieneazide linker enables the facile connection of Li+@C60 with small molecules bearing a terminal alkyne via Huisgen annulation and a subsequent Diels-Alder reaction.",

author = "Shogo Fujiki and Takumi Takada and Shota Nagasawa and Hiroshi Okada and Yusuke Sasano and Eunsang Kwon and Yutaka Matsuo and Yoshiharu Iwabuchi",

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AU - Fujiki, Shogo

AU - Takada, Takumi

AU - Nagasawa, Shota

AU - Okada, Hiroshi

AU - Sasano, Yusuke

AU - Kwon, Eunsang

AU - Matsuo, Yutaka

AU - Iwabuchi, Yoshiharu

PY - 2023/1/4

Y1 - 2023/1/4

N2 - A versatile method for the chemical modification of a lithium-ion endohedral fullerene (Li+@C60) to connect various small molecules is described. The designed dieneazide linker enables the facile connection of Li+@C60 with small molecules bearing a terminal alkyne via Huisgen annulation and a subsequent Diels-Alder reaction.

AB - A versatile method for the chemical modification of a lithium-ion endohedral fullerene (Li+@C60) to connect various small molecules is described. The designed dieneazide linker enables the facile connection of Li+@C60 with small molecules bearing a terminal alkyne via Huisgen annulation and a subsequent Diels-Alder reaction.

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Sequential click modification of a lithium-ion endohedral fullerene connecting small molecules through a dieneazide linker

Abstract

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