Separation of thorium and uranium by sulfide method

For the recovery of nuclear materials from spent fuel, a novel reprocessing process based on sulfide chemistry has been proposed. In this paper, the sulfurization behavior of thorium and uranium oxides was studied using carbon disulfide. When U₃O₈ was reacted with CS₂, it was reduced to UO₂ at temperatures lower than 673 K, while sulfuruization of UO₂ was observed at temperatures higher than 773 K forming UOS and US₂. On the other hand, no reaction was observed for ThO₂ up to 773 K. Similar results were obtained for the mixture of U₃O₈ and ThO₂. The obtained results were also compared with thermodynamic consideration. Then, separation of uranium from thorium was suggested by selective sulfurization of uranium oxides. Finally, it was summarized that most of thorium oxide could be recovered as ThO₂ after the separation of sulfurized uranium oxides.