Separation of Am and Cm by using TODGA and DOODA(C8) adsorbents with hydrophilic ligand-nitric acid solution

Shigekazu Usuda; Kei Yamanishi; Hitoshi Mimura; Yuji Sasaki; Akira Kirishima; Nobuaki Sato; Yuichi Niibori

doi:10.1007/s10967-014-3481-7

Separation of Am and Cm by using TODGA and DOODA(C8) adsorbents with hydrophilic ligand-nitric acid solution

Shigekazu Usuda, Kei Yamanishi, Hitoshi Mimura, Yuji Sasaki, Akira Kirishima, Nobuaki Sato, Yuichi Niibori

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Extraction chromatographic separation of trivalent minor actinides (MA: Am and Cm) was investigated by using solid adsorbents impregnating the lipophilic diamide-type ligands, TODGA (N,N,N′,N′-tetraoctyl-3-oxapentane-1,5-diamide) and DOODA(C8) (N,N,N′,N′-tetraoctyl-3,6-dioxaoctane-1,8-diamide). In nitric acid eluents, hydrophilic diamide-type ligands, DOODA(C2) (N,N,N′,N′-tetraethyl-3,6-dioxaoctanediamide) and TEDGA (N,N,N’,N’-tetraethyl-diglycolamide) were included for the respective adsorbents as masking agents in order to produce a synergistic effect in mutual separation of Am and Cm. The adsorption tendency of Am and Cm for the adsorbents was opposite each other, that was similar to the case of lanthanides.

Original language	English
Pages (from-to)	1351-1355
Number of pages	5
Journal	Journal of Radioanalytical and Nuclear Chemistry
Volume	303
Issue number	2
DOIs	https://doi.org/10.1007/s10967-014-3481-7
Publication status	Published - 2015 Feb

Keywords

Am and Cm
Chromatographic separation
Hydrophilic DOODA(C2) and TEDGA ligands
Synergistic effect
TODGA and DOODA(C8) adsorbents

ASJC Scopus subject areas

Analytical Chemistry
Nuclear Energy and Engineering
Radiology Nuclear Medicine and imaging
Pollution
Spectroscopy
Public Health, Environmental and Occupational Health
Health, Toxicology and Mutagenesis

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1007/s10967-014-3481-7

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Separation of Am and Cm by using TODGA and DOODA(C8) adsorbents with hydrophilic ligand-nitric acid solution. / Usuda, Shigekazu; Yamanishi, Kei; Mimura, Hitoshi; Sasaki, Yuji; Kirishima, Akira; Sato, Nobuaki; Niibori, Yuichi.

In: Journal of Radioanalytical and Nuclear Chemistry, Vol. 303, No. 2, 02.2015, p. 1351-1355.

Research output: Contribution to journal › Article › peer-review

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title = "Separation of Am and Cm by using TODGA and DOODA(C8) adsorbents with hydrophilic ligand-nitric acid solution",

abstract = "Extraction chromatographic separation of trivalent minor actinides (MA: Am and Cm) was investigated by using solid adsorbents impregnating the lipophilic diamide-type ligands, TODGA (N,N,N′,N′-tetraoctyl-3-oxapentane-1,5-diamide) and DOODA(C8) (N,N,N′,N′-tetraoctyl-3,6-dioxaoctane-1,8-diamide). In nitric acid eluents, hydrophilic diamide-type ligands, DOODA(C2) (N,N,N′,N′-tetraethyl-3,6-dioxaoctanediamide) and TEDGA (N,N,N{\textquoteright},N{\textquoteright}-tetraethyl-diglycolamide) were included for the respective adsorbents as masking agents in order to produce a synergistic effect in mutual separation of Am and Cm. The adsorption tendency of Am and Cm for the adsorbents was opposite each other, that was similar to the case of lanthanides.",

keywords = "Am and Cm, Chromatographic separation, Hydrophilic DOODA(C2) and TEDGA ligands, Synergistic effect, TODGA and DOODA(C8) adsorbents",

author = "Shigekazu Usuda and Kei Yamanishi and Hitoshi Mimura and Yuji Sasaki and Akira Kirishima and Nobuaki Sato and Yuichi Niibori",

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AU - Yamanishi, Kei

AU - Mimura, Hitoshi

AU - Sasaki, Yuji

AU - Kirishima, Akira

AU - Sato, Nobuaki

AU - Niibori, Yuichi

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N2 - Extraction chromatographic separation of trivalent minor actinides (MA: Am and Cm) was investigated by using solid adsorbents impregnating the lipophilic diamide-type ligands, TODGA (N,N,N′,N′-tetraoctyl-3-oxapentane-1,5-diamide) and DOODA(C8) (N,N,N′,N′-tetraoctyl-3,6-dioxaoctane-1,8-diamide). In nitric acid eluents, hydrophilic diamide-type ligands, DOODA(C2) (N,N,N′,N′-tetraethyl-3,6-dioxaoctanediamide) and TEDGA (N,N,N’,N’-tetraethyl-diglycolamide) were included for the respective adsorbents as masking agents in order to produce a synergistic effect in mutual separation of Am and Cm. The adsorption tendency of Am and Cm for the adsorbents was opposite each other, that was similar to the case of lanthanides.

AB - Extraction chromatographic separation of trivalent minor actinides (MA: Am and Cm) was investigated by using solid adsorbents impregnating the lipophilic diamide-type ligands, TODGA (N,N,N′,N′-tetraoctyl-3-oxapentane-1,5-diamide) and DOODA(C8) (N,N,N′,N′-tetraoctyl-3,6-dioxaoctane-1,8-diamide). In nitric acid eluents, hydrophilic diamide-type ligands, DOODA(C2) (N,N,N′,N′-tetraethyl-3,6-dioxaoctanediamide) and TEDGA (N,N,N’,N’-tetraethyl-diglycolamide) were included for the respective adsorbents as masking agents in order to produce a synergistic effect in mutual separation of Am and Cm. The adsorption tendency of Am and Cm for the adsorbents was opposite each other, that was similar to the case of lanthanides.

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Separation of Am and Cm by using TODGA and DOODA(C8) adsorbents with hydrophilic ligand-nitric acid solution

Abstract

Keywords

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UN SDGs

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