Self-assembly of M 24L 48 polyhedra based on empirical prediction

Jens Bunzen; Junji Iwasa; Pia Bonakdarzadeh; Eri Numata; Kari Rissanen; Sota Sato; Makoto Fujita

doi:10.1002/anie.201108731

Self-assembly of M ₂₄L ₄₈ polyhedra based on empirical prediction

Jens Bunzen, Junji Iwasa, Pia Bonakdarzadeh, Eri Numata, Kari Rissanen, Sota Sato, Makoto Fujita

Research output: Contribution to journal › Article › peer-review

113 Citations (Scopus)

Abstract

Critical structural switch: A small initial difference in the angle within bidentate ligands (see scheme) is amplified into an incommensurable difference in the resultant structures (M ₁₂L ₂₄ or M ₂₄L ₄₈). This molecular-level emergent behavior was predicted from the empirical threshold of the ligand bend angle, determined by a ligand mixing experiment, for the critical M ₁₂L ₂₄/M ₂₄L ₄₈ switchover.

Original language	English
Pages (from-to)	3161-3163
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	13
DOIs	https://doi.org/10.1002/anie.201108731
Publication status	Published - 2012 Mar 26

Keywords

palladium
pyrroles
self-assembly
spherical structures

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Access to Document

10.1002/anie.201108731

Cite this

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abstract = "Critical structural switch: A small initial difference in the angle within bidentate ligands (see scheme) is amplified into an incommensurable difference in the resultant structures (M 12L 24 or M 24L 48). This molecular-level emergent behavior was predicted from the empirical threshold of the ligand bend angle, determined by a ligand mixing experiment, for the critical M 12L 24/M 24L 48 switchover.",

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AU - Rissanen, Kari

AU - Sato, Sota

AU - Fujita, Makoto

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