Selective Si-C bond cleavage on a diorganosilicon porphyrin complex bearing different axial ligands

Shintaro Ishida, Kimio Yoshimura, Hideyuki Matsumoto, Soichiro Kyushin

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Tetraphenylporphyrinato methylphenylsilicon complex (abbreviated to Si(TPP)MePh) was synthesized and structurally characterized. Although the Si-Ph bond of Si(TPP)MePh is much longer than the Si-Me bond, photolysis and chemical oxidation of Si(TPP)MePh cleaved the Si-Me bond selectively and gave new phenyl-substituted silicon porphyrins. Theoretical studies of a model compound showed that significant σ-π orbital interaction raised the HOMO and is responsible for the silicon-carbon bond cleavage. The instability of phenyl radical to methyl radical caused selective bond cleavage.

Original languageEnglish
Pages (from-to)362-363
Number of pages2
JournalChemistry Letters
Volume38
Issue number4
DOIs
Publication statusPublished - 2009 Jul 20
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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