@article{089e6c5aa82b49bfb83798114159d54c,
title = "Selective Reduction of Nitrate by a Local Cell Catalyst Composed of Metal-Doped Covalent Triazine Frameworks",
abstract = "So-called local cells resulting from the coupling of oxidation and reduction reactions on the same conductive substrate represent a well-known cause of metallic corrosion. In the present study, we attempted to demonstrate that catalytic systems based on the principle of local cell reactions can be successfully fabricated using metal-doped covalent triazine frameworks as catalytic units. A conductive substrate carrying platinum- and copper-doped covalent triazine frameworks as catalysts for the oxidation and reduction processes, respectively, was developed to fabricate a local cell catalytic unit for the concurrent reduction of nitrate to nitrous oxide and oxidation of hydrogen.",
keywords = "covalent triazine frameworks, electrocatalysts, local cell reaction, nitrate reduction, single-atom catalyst",
author = "Kazuhide Kamiya and Tomomi Tatebe and Shuhei Yamamura and Kazuyuki Iwase and Takashi Harada and Shuji Nakanishi",
note = "Funding Information: This research was supported by the PRESTO Program of the Japan Science and Technology Agency (JST) (JPMJPR1415) and a Grant-in-Aid for Young Scientists (A) (17H04798). Synchrotron radiation experiments were performed at the BL01B1 and BL14B2 beamlines of SPring-8 with the approval of the Japan Synchrotron Radiation Research Institute (JASRI; Proposal nos. 2016B1098, 2016B1696, 2017A1790, and 2017B1171). TEM measurement was carried out by using a facility in the Research Center for Ultra-High Voltage Electron Microscopy, Osaka University and TEM observation was supported by Dr. Takao Sakata. Funding Information: This research was supported by the PRESTO Program of the Japan Science and Technology Agency (JST) (JPMJPR1415) and a Grant-in-Aid for Young Scientists (A) (17H04798). Synchrotron radiation experiments were performed at the BL01B1 and BL14B2 beamlines of SPring-8 with the approval of the Japan Synchrotron Radiation Research Institute (JASRI; Proposal nos. 2016B1098, 2016B1696, 2017A1790, and 2017B1171). TEM measurement was carried out by using a facility in the Research Center for Ultra-High Voltage Electron Microscopy, Osaka University, and TEM observation was supported by Dr. Takao Sakata. Publisher Copyright: {\textcopyright} 2018 American Chemical Society.",
year = "2018",
month = apr,
day = "6",
doi = "10.1021/acscatal.7b04465",
language = "English",
volume = "8",
pages = "2693--2698",
journal = "ACS Catalysis",
issn = "2155-5435",
publisher = "American Chemical Society",
number = "4",
}