Selective reactions of minor tautomers among allylic type triorganoboranes

Ilya D. Gridnev, Mikhail E. Gurskii, Yuri N. Bubnov

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

Due to the facile 1,3-B sigmatropic shifts and other skeletal rearrangements facilitated by the 2p atomic orbital of the boron atom, fast equilibria between several tautomeric forms are characteristic for allylic triorganoboranes. Spectrally the most thermodynamically stable isomers are observed, whereas the minor more reactive tautomers often participate in chemical transformations.

Original languageEnglish
Pages (from-to)98-102
Number of pages5
JournalJournal of Organometallic Chemistry
Volume581
Issue number1-2
DOIs
Publication statusPublished - 1999 Jun 5
Externally publishedYes

Keywords

  • Sigmatropic shift
  • Structural lability
  • Triorganoboranes

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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