Selective ligation to sterically isolated metallophthalocyanines

Mutsumi Kimura; Ayumu Sakaguchi; Kazuchika Ohta; Kenji Hanabusa; Hirofusa Shirai; Nagao Kobayashi

doi:10.1021/ic026149o

Selective ligation to sterically isolated metallophthalocyanines

Mutsumi Kimura, Ayumu Sakaguchi, Kazuchika Ohta, Kenji Hanabusa, Hirofusa Shirai, Nagao Kobayashi

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

A new class of sterically hindered phthalocyanine has been synthesized and characterized. Pentaphenylbenzene units were introduced at the periphery of each phthalocyanine to yield a sterically protected metal center. The attachment of the bulky oligophenylbenzene units resulted in the complete isolation of individual MPc molecules. The pockets around a cobalt center affect selectivity in the ligation of pyridines that have different sizes and shapes.

Original language	English
Pages (from-to)	2821-2823
Number of pages	3
Journal	Inorganic chemistry
Volume	42
Issue number	9
DOIs	https://doi.org/10.1021/ic026149o
Publication status	Published - 2003 May 5

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

Access to Document

10.1021/ic026149o

Cite this

@article{ba6ef60cb38447a9afbda801bdeec17c,

title = "Selective ligation to sterically isolated metallophthalocyanines",

abstract = "A new class of sterically hindered phthalocyanine has been synthesized and characterized. Pentaphenylbenzene units were introduced at the periphery of each phthalocyanine to yield a sterically protected metal center. The attachment of the bulky oligophenylbenzene units resulted in the complete isolation of individual MPc molecules. The pockets around a cobalt center affect selectivity in the ligation of pyridines that have different sizes and shapes.",

author = "Mutsumi Kimura and Ayumu Sakaguchi and Kazuchika Ohta and Kenji Hanabusa and Hirofusa Shirai and Nagao Kobayashi",

year = "2003",

month = may,

day = "5",

doi = "10.1021/ic026149o",

language = "English",

volume = "42",

pages = "2821--2823",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "9",

}

TY - JOUR

T1 - Selective ligation to sterically isolated metallophthalocyanines

AU - Kimura, Mutsumi

AU - Sakaguchi, Ayumu

AU - Ohta, Kazuchika

AU - Hanabusa, Kenji

AU - Shirai, Hirofusa

AU - Kobayashi, Nagao

PY - 2003/5/5

Y1 - 2003/5/5

N2 - A new class of sterically hindered phthalocyanine has been synthesized and characterized. Pentaphenylbenzene units were introduced at the periphery of each phthalocyanine to yield a sterically protected metal center. The attachment of the bulky oligophenylbenzene units resulted in the complete isolation of individual MPc molecules. The pockets around a cobalt center affect selectivity in the ligation of pyridines that have different sizes and shapes.

AB - A new class of sterically hindered phthalocyanine has been synthesized and characterized. Pentaphenylbenzene units were introduced at the periphery of each phthalocyanine to yield a sterically protected metal center. The attachment of the bulky oligophenylbenzene units resulted in the complete isolation of individual MPc molecules. The pockets around a cobalt center affect selectivity in the ligation of pyridines that have different sizes and shapes.

UR - http://www.scopus.com/inward/record.url?scp=0037624492&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037624492&partnerID=8YFLogxK

U2 - 10.1021/ic026149o

DO - 10.1021/ic026149o

M3 - Article

C2 - 12716168

AN - SCOPUS:0037624492

VL - 42

SP - 2821

EP - 2823

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 9

ER -

Selective ligation to sterically isolated metallophthalocyanines

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this