Selective Hydrodeoxygenation of 2-Furancarboxylic Acid to Valeric Acid over Molybdenum-Oxide-Modified Platinum Catalyst

Takehiro Asano; Masazumi Tamura; Yoshinao Nakagawa; Keiichi Tomishige

doi:10.1021/acssuschemeng.6b01640

Selective Hydrodeoxygenation of 2-Furancarboxylic Acid to Valeric Acid over Molybdenum-Oxide-Modified Platinum Catalyst

Takehiro Asano, Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige

ENG - Applied Chemistry

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

2-Furancarboxylic acid (FCA), produced by oxidation of furfural, is rarely used as a platform molecule. Metal-oxide-supported Pt-MoO_x catalysts were effective for hydrodeoxygenation of FCA to valeric acid (VA) in water solvent. The highest VA yield is 51% over Pt-MoO_x/TiO₂ catalyst under 1.5 MPa H₂ at 413 K. Other metal combinations (M-MoO_x, M = Rh, Pd, Ru, Ir, Au, none; Pt-M'O_x, M'= V, W, Re, none) showed very low VA yield. This catalyst system was applicable to the hydrodeoxygenation of 2,5-furandicarboxylic acid (FDCA), and adipic acid (AA) was obtained with 21% yield at 473 K.

Original language	English
Pages (from-to)	6253-6257
Number of pages	5
Journal	ACS Sustainable Chemistry and Engineering
Volume	4
Issue number	12
DOIs	https://doi.org/10.1021/acssuschemeng.6b01640
Publication status	Published - 2016 Dec 5

Keywords

2-Furancarboxylic acid
Bimetallic catalyst
Biomass
Molybdenum
Platinum

ASJC Scopus subject areas

Chemistry(all)
Environmental Chemistry
Chemical Engineering(all)
Renewable Energy, Sustainability and the Environment

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1021/acssuschemeng.6b01640

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title = "Selective Hydrodeoxygenation of 2-Furancarboxylic Acid to Valeric Acid over Molybdenum-Oxide-Modified Platinum Catalyst",

abstract = "2-Furancarboxylic acid (FCA), produced by oxidation of furfural, is rarely used as a platform molecule. Metal-oxide-supported Pt-MoOx catalysts were effective for hydrodeoxygenation of FCA to valeric acid (VA) in water solvent. The highest VA yield is 51% over Pt-MoOx/TiO2 catalyst under 1.5 MPa H2 at 413 K. Other metal combinations (M-MoOx, M = Rh, Pd, Ru, Ir, Au, none; Pt-M'Ox, M'= V, W, Re, none) showed very low VA yield. This catalyst system was applicable to the hydrodeoxygenation of 2,5-furandicarboxylic acid (FDCA), and adipic acid (AA) was obtained with 21% yield at 473 K.",

keywords = "2-Furancarboxylic acid, Bimetallic catalyst, Biomass, Molybdenum, Platinum",

author = "Takehiro Asano and Masazumi Tamura and Yoshinao Nakagawa and Keiichi Tomishige",

note = "Funding Information: A part of this work is supported by the JSPS KAKENHI grant number 26249121. We also appreciate the Technical Division in School of Engineering in Tohoku University for STEM measurements. Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

year = "2016",

month = dec,

day = "5",

doi = "10.1021/acssuschemeng.6b01640",

language = "English",

volume = "4",

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journal = "ACS Sustainable Chemistry and Engineering",

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TY - JOUR

T1 - Selective Hydrodeoxygenation of 2-Furancarboxylic Acid to Valeric Acid over Molybdenum-Oxide-Modified Platinum Catalyst

AU - Asano, Takehiro

AU - Tamura, Masazumi

AU - Nakagawa, Yoshinao

AU - Tomishige, Keiichi

N1 - Funding Information: A part of this work is supported by the JSPS KAKENHI grant number 26249121. We also appreciate the Technical Division in School of Engineering in Tohoku University for STEM measurements. Publisher Copyright: © 2016 American Chemical Society.

PY - 2016/12/5

Y1 - 2016/12/5

N2 - 2-Furancarboxylic acid (FCA), produced by oxidation of furfural, is rarely used as a platform molecule. Metal-oxide-supported Pt-MoOx catalysts were effective for hydrodeoxygenation of FCA to valeric acid (VA) in water solvent. The highest VA yield is 51% over Pt-MoOx/TiO2 catalyst under 1.5 MPa H2 at 413 K. Other metal combinations (M-MoOx, M = Rh, Pd, Ru, Ir, Au, none; Pt-M'Ox, M'= V, W, Re, none) showed very low VA yield. This catalyst system was applicable to the hydrodeoxygenation of 2,5-furandicarboxylic acid (FDCA), and adipic acid (AA) was obtained with 21% yield at 473 K.

AB - 2-Furancarboxylic acid (FCA), produced by oxidation of furfural, is rarely used as a platform molecule. Metal-oxide-supported Pt-MoOx catalysts were effective for hydrodeoxygenation of FCA to valeric acid (VA) in water solvent. The highest VA yield is 51% over Pt-MoOx/TiO2 catalyst under 1.5 MPa H2 at 413 K. Other metal combinations (M-MoOx, M = Rh, Pd, Ru, Ir, Au, none; Pt-M'Ox, M'= V, W, Re, none) showed very low VA yield. This catalyst system was applicable to the hydrodeoxygenation of 2,5-furandicarboxylic acid (FDCA), and adipic acid (AA) was obtained with 21% yield at 473 K.

KW - 2-Furancarboxylic acid

KW - Bimetallic catalyst

KW - Biomass

KW - Molybdenum

KW - Platinum

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JO - ACS Sustainable Chemistry and Engineering

JF - ACS Sustainable Chemistry and Engineering

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ER -

Selective Hydrodeoxygenation of 2-Furancarboxylic Acid to Valeric Acid over Molybdenum-Oxide-Modified Platinum Catalyst

Abstract

Keywords

ASJC Scopus subject areas

UN SDGs

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