Selective electrocatalytic oxidation of primary and secondary alcohols mediated by decahydroquinolinyl-N-oxyl radical

Yoshitomo Kashiwagi, Futoshi Kurashima, Jun Ichi Anzai, Tesuo Osa

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

(±)-cis,cis-4-Benzoyloxy-2,2,8a-trimethyldecahydroquinolinyl-N-oxyl reveals a reversible redox peak whose oxidation potential is at + 0.67 V vs. Ag/AgCl. The compound catalyzed the selective oxidation reactions of primary and secondary alcohols to aldehydes and ketones, respectively, in high current efficiency (86.492.7%) and selectivity (100%).

Original languageEnglish
Pages (from-to)1945-1948
Number of pages4
JournalHeterocycles
Volume51
Issue number8
DOIs
Publication statusPublished - 1999 Aug 1

ASJC Scopus subject areas

  • Analytical Chemistry
  • Pharmacology
  • Organic Chemistry

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