Selective cross-coupling of amines by alumina-supported palladium nanocluster catalysts

Ken ichi Shimizu; Katsuya Shimura; Keiichiro Ohshima; Masazumi Tamura; Atsushi Satsuma

doi:10.1039/c1gc15835j

Selective cross-coupling of amines by alumina-supported palladium nanocluster catalysts

Ken ichi Shimizu, Katsuya Shimura, Keiichiro Ohshima, Masazumi Tamura, Atsushi Satsuma

ENG - Applied Chemistry

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

Al₂O₃-supported Pd nanoclusters with an average particle size of 1.8 nm act as a reusable catalyst for the selective cross-coupling of amines. The reaction is a structure-sensitive reaction, demanding coordinatively unsaturated Pd atoms on a metallic nanocluster. The support also affects the activity, an amphoteric oxide (Al₂O₃) is most effective.

Original language	English
Pages (from-to)	3096-3100
Number of pages	5
Journal	Green Chemistry
Volume	13
Issue number	11
DOIs	https://doi.org/10.1039/c1gc15835j
Publication status	Published - 2011 Jan 11

ASJC Scopus subject areas

Environmental Chemistry
Pollution

Access to Document

10.1039/c1gc15835j

Cite this

@article{9280dc32db804ed4a135052275782c8e,

title = "Selective cross-coupling of amines by alumina-supported palladium nanocluster catalysts",

abstract = "Al2O3-supported Pd nanoclusters with an average particle size of 1.8 nm act as a reusable catalyst for the selective cross-coupling of amines. The reaction is a structure-sensitive reaction, demanding coordinatively unsaturated Pd atoms on a metallic nanocluster. The support also affects the activity, an amphoteric oxide (Al2O3) is most effective.",

author = "Shimizu, {Ken ichi} and Katsuya Shimura and Keiichiro Ohshima and Masazumi Tamura and Atsushi Satsuma",

year = "2011",

month = jan,

day = "11",

doi = "10.1039/c1gc15835j",

language = "English",

volume = "13",

pages = "3096--3100",

journal = "Green Chemistry",

issn = "1463-9262",

publisher = "Royal Society of Chemistry",

number = "11",

}

TY - JOUR

T1 - Selective cross-coupling of amines by alumina-supported palladium nanocluster catalysts

AU - Shimizu, Ken ichi

AU - Shimura, Katsuya

AU - Ohshima, Keiichiro

AU - Tamura, Masazumi

AU - Satsuma, Atsushi

PY - 2011/1/11

Y1 - 2011/1/11

N2 - Al2O3-supported Pd nanoclusters with an average particle size of 1.8 nm act as a reusable catalyst for the selective cross-coupling of amines. The reaction is a structure-sensitive reaction, demanding coordinatively unsaturated Pd atoms on a metallic nanocluster. The support also affects the activity, an amphoteric oxide (Al2O3) is most effective.

AB - Al2O3-supported Pd nanoclusters with an average particle size of 1.8 nm act as a reusable catalyst for the selective cross-coupling of amines. The reaction is a structure-sensitive reaction, demanding coordinatively unsaturated Pd atoms on a metallic nanocluster. The support also affects the activity, an amphoteric oxide (Al2O3) is most effective.

UR - http://www.scopus.com/inward/record.url?scp=80455141699&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=80455141699&partnerID=8YFLogxK

U2 - 10.1039/c1gc15835j

DO - 10.1039/c1gc15835j

M3 - Article

AN - SCOPUS:80455141699

VL - 13

SP - 3096

EP - 3100

JO - Green Chemistry

JF - Green Chemistry

SN - 1463-9262

IS - 11

ER -

Selective cross-coupling of amines by alumina-supported palladium nanocluster catalysts

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this