Selective cross-coupling of amines by alumina-supported palladium nanocluster catalysts

Ken ichi Shimizu; Katsuya Shimura; Keiichiro Ohshima; Masazumi Tamura; Atsushi Satsuma

doi:10.1039/c1gc15835j

Selective cross-coupling of amines by alumina-supported palladium nanocluster catalysts

Ken ichi Shimizu, Katsuya Shimura, Keiichiro Ohshima, Masazumi Tamura, Atsushi Satsuma

ENG - Applied Chemistry

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

Al₂O₃-supported Pd nanoclusters with an average particle size of 1.8 nm act as a reusable catalyst for the selective cross-coupling of amines. The reaction is a structure-sensitive reaction, demanding coordinatively unsaturated Pd atoms on a metallic nanocluster. The support also affects the activity, an amphoteric oxide (Al₂O₃) is most effective.

Original language	English
Pages (from-to)	3096-3100
Number of pages	5
Journal	Green Chemistry
Volume	13
Issue number	11
DOIs	https://doi.org/10.1039/c1gc15835j
Publication status	Published - 2011 Jan 11

ASJC Scopus subject areas

Environmental Chemistry
Pollution

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abstract = "Al2O3-supported Pd nanoclusters with an average particle size of 1.8 nm act as a reusable catalyst for the selective cross-coupling of amines. The reaction is a structure-sensitive reaction, demanding coordinatively unsaturated Pd atoms on a metallic nanocluster. The support also affects the activity, an amphoteric oxide (Al2O3) is most effective.",

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AU - Satsuma, Atsushi

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N2 - Al2O3-supported Pd nanoclusters with an average particle size of 1.8 nm act as a reusable catalyst for the selective cross-coupling of amines. The reaction is a structure-sensitive reaction, demanding coordinatively unsaturated Pd atoms on a metallic nanocluster. The support also affects the activity, an amphoteric oxide (Al2O3) is most effective.

AB - Al2O3-supported Pd nanoclusters with an average particle size of 1.8 nm act as a reusable catalyst for the selective cross-coupling of amines. The reaction is a structure-sensitive reaction, demanding coordinatively unsaturated Pd atoms on a metallic nanocluster. The support also affects the activity, an amphoteric oxide (Al2O3) is most effective.

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Selective cross-coupling of amines by alumina-supported palladium nanocluster catalysts

Abstract

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