Secure route to the epoxybicyclo[7.3.0]dodecadienediyne core of the kedarcidin chromophore

Kouki Ogawa, Yasuhito Koyama, Isao Ohashi, Itaru Sato, Masahiro Hirama

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

Formation of an epoxide before 9-membered ring cyclization and SmI 2 mediated reductive olefination in the presence of the epoxide successfully produced the epoxybicyclo[7.3.0]dodecadienediyne core of the kedarcidin chromophore.

Original languageEnglish
Pages (from-to)6327-6329
Number of pages3
JournalChemical Communications
Issue number47
DOIs
Publication statusPublished - 2008 Dec 11

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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