Abstract
Treatment of Ru(xantsil)(CO)(η6-toluene) (1) [xantsil = (9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)] with PCy3 led to the formation of Ru(xantsil)(CO)(PCy3) (3), in which the xantsil ligand is bound to the ruthenium center in K3(Si,Si,O) fashion. The highly coordinatively unsaturated nature of 3 is indicated by the reaction with CO to give Ru(xantsil)(CO)3(PCy3) (5).
Original language | English |
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Pages (from-to) | 4531-4533 |
Number of pages | 3 |
Journal | Organometallics |
Volume | 23 |
Issue number | 20 |
DOIs | |
Publication status | Published - 2004 Sep 27 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry