Rotational effect on SRVL nonradiative transitions: Linewidth and Coriolis coupling

H. Kono; S. H. Lin; E. W. Schlag

doi:10.1063/1.444396

Rotational effect on SRVL nonradiative transitions: Linewidth and Coriolis coupling

H. Kono, S. H. Lin, E. W. Schlag

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

In the present paper, we discuss the rotational effect on interval conversion due to the linewidths and the Coriolis coupling in the final electronic state. For a formaldehyde model system, some numerical results of the rotational effect will be reported. It will be seen that the Coriolis coupling plays an important role in small linewidth cases. The numerical results also include the effect of the vibration-rotation coupling through the change of moments of inertia; the change of the geometry shifts between two electronic states due to this coupling is calculated numerically.

Original language	English
Pages (from-to)	4474-4483
Number of pages	10
Journal	The Journal of Chemical Physics
Volume	77
Issue number	9
DOIs	https://doi.org/10.1063/1.444396
Publication status	Published - 1982 Jan 1

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

Access to Document

10.1063/1.444396

Fingerprint Dive into the research topics of 'Rotational effect on SRVL nonradiative transitions: Linewidth and Coriolis coupling'. Together they form a unique fingerprint.

Cite this

@article{295909d9f4ce4b939e8d093f3dfb6cbb,

title = "Rotational effect on SRVL nonradiative transitions: Linewidth and Coriolis coupling",

abstract = "In the present paper, we discuss the rotational effect on interval conversion due to the linewidths and the Coriolis coupling in the final electronic state. For a formaldehyde model system, some numerical results of the rotational effect will be reported. It will be seen that the Coriolis coupling plays an important role in small linewidth cases. The numerical results also include the effect of the vibration-rotation coupling through the change of moments of inertia; the change of the geometry shifts between two electronic states due to this coupling is calculated numerically.",

author = "H. Kono and Lin, {S. H.} and Schlag, {E. W.}",

year = "1982",

month = jan,

day = "1",

doi = "10.1063/1.444396",

language = "English",

volume = "77",

pages = "4474--4483",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics Publising LLC",

number = "9",

}

TY - JOUR

T1 - Rotational effect on SRVL nonradiative transitions

T2 - Linewidth and Coriolis coupling

AU - Kono, H.

AU - Lin, S. H.

AU - Schlag, E. W.

PY - 1982/1/1

Y1 - 1982/1/1

N2 - In the present paper, we discuss the rotational effect on interval conversion due to the linewidths and the Coriolis coupling in the final electronic state. For a formaldehyde model system, some numerical results of the rotational effect will be reported. It will be seen that the Coriolis coupling plays an important role in small linewidth cases. The numerical results also include the effect of the vibration-rotation coupling through the change of moments of inertia; the change of the geometry shifts between two electronic states due to this coupling is calculated numerically.

AB - In the present paper, we discuss the rotational effect on interval conversion due to the linewidths and the Coriolis coupling in the final electronic state. For a formaldehyde model system, some numerical results of the rotational effect will be reported. It will be seen that the Coriolis coupling plays an important role in small linewidth cases. The numerical results also include the effect of the vibration-rotation coupling through the change of moments of inertia; the change of the geometry shifts between two electronic states due to this coupling is calculated numerically.

UR - http://www.scopus.com/inward/record.url?scp=33646072710&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33646072710&partnerID=8YFLogxK

U2 - 10.1063/1.444396

DO - 10.1063/1.444396

M3 - Article

AN - SCOPUS:33646072710

VL - 77

SP - 4474

EP - 4483

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

SN - 0021-9606

IS - 9

ER -