Rotational analysis for the doppler-free photoelectron spectrum of water using the spectator model

Mark S. Ford, Klaus Müller-Dethlefs, M. Kitajima, H. Tanaka, Y. Tamenori, A. De Fanis, Kyoshi Ueda

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

A photoelectron spectrum of H2O has been recorded at a resolution of 2 meV under Doppler-free conditions. Complex rotational structures appear in the individual vibrational states of the electronic X̃ + 2B1 and Ã+ 2A2 states in H2O+. The rotational structures are analyzed and well reproduced using a spectator orbital model developed for rotationally resolved photoelectron spectroscopy.

Original languageEnglish
Pages (from-to)11133-11138
Number of pages6
JournalJournal of Physical Chemistry A
Volume114
Issue number42
DOIs
Publication statusPublished - 2010 Oct 28

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

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