Rhodium-catalyzed thiophosphinylation and phosphinylation reactions of disulfides and diselenides

Mieko Arisawa, Tetsuya Ono, Masahiko Yamaguchi

Research output: Contribution to journalArticlepeer-review

44 Citations (Scopus)

Abstract

Alkyl and aryl dithiophosphinates were synthesized by the reaction of disulfides with biphosphine disulfides in the presence of RhH(PPh 3)4 and 1,2-diphenylphosphinoethane (dppe). The catalyst also promoted synthesis of thiophosphinates and selenothiophosphinates from disulfides and diselenides.

Original languageEnglish
Pages (from-to)5669-5671
Number of pages3
JournalTetrahedron Letters
Volume46
Issue number34
DOIs
Publication statusPublished - 2005 Aug 22

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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