Abstract
A rhodium complex catalyzed C−Se bond formation between diheteroaryl diselenides and acid fluorides in the presence of triphenylphosphine to provide heteroarylselenyl esters in good yields. The reaction was applicable to five- and six-membered heteroaryl compounds. The heteroarylselenyl esters can be used as heteroaryselenating reagents in the synthesis of heteroaryl selenides, as shown by a platinum-catalyzed addition reaction with 1-octyne.
Original language | English |
---|---|
Pages (from-to) | 553-556 |
Number of pages | 4 |
Journal | Asian Journal of Organic Chemistry |
Volume | 9 |
Issue number | 4 |
DOIs | |
Publication status | Published - 2020 Apr 1 |
Keywords
- Acid fluorides
- C−Se bond formation
- Diheteroaryl diselenides
- Heteroarylselenyl esters
- Heteroaryselenating reagents
ASJC Scopus subject areas
- Organic Chemistry