Rhodium-Catalyzed Synthesis of Heteroarylselenyl Esters from Diheteroaryl Diselenides and Acid Fluorides

Mieko Arisawa, Ren Suzuki, Keiichiro Ohashi, Masahiko Yamaguchi

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

A rhodium complex catalyzed C−Se bond formation between diheteroaryl diselenides and acid fluorides in the presence of triphenylphosphine to provide heteroarylselenyl esters in good yields. The reaction was applicable to five- and six-membered heteroaryl compounds. The heteroarylselenyl esters can be used as heteroaryselenating reagents in the synthesis of heteroaryl selenides, as shown by a platinum-catalyzed addition reaction with 1-octyne.

Original languageEnglish
Pages (from-to)553-556
Number of pages4
JournalAsian Journal of Organic Chemistry
Volume9
Issue number4
DOIs
Publication statusPublished - 2020 Apr 1

Keywords

  • Acid fluorides
  • C−Se bond formation
  • Diheteroaryl diselenides
  • Heteroarylselenyl esters
  • Heteroaryselenating reagents

ASJC Scopus subject areas

  • Organic Chemistry

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