Rhodium-Catalyzed Synthesis of Dialkyl(Heteroaryl)Phosphine Sulfides by Phosphinylation of Heteroaryl Sulfides

Mieko Arisawa, Takeru Tazawa, Wataru Ichinose, Haruki Kobayashi, Masahiko Yamaguchi

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Dialkyl(heteroaryl)phosphine sulfides were synthesized by the rhodium-catalyzed exchange reaction of heteroaryl aryl sulfides and tetraalkyldiphosphine disulfides. The reaction has a broad applicability, giving diverse dialkyl(heteroaryl)phosphine sulfides containing five- and six-membered heteroaryl groups. Various dialkyl(heteroaryl)phosphines were obtained by desulfurization. (Figure presented.).

Original languageEnglish
Pages (from-to)3488-3491
Number of pages4
JournalAdvanced Synthesis and Catalysis
Volume360
Issue number18
DOIs
Publication statusPublished - 2018 Sep 17

Keywords

  • Rh catalysis
  • desulfurization
  • dialkyl(heteroaryl)phosphine sulfides
  • phosphinylation
  • tetraalkyldiphosphine disulfides

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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